I would first try to cycle a dummy round. If it chambers and ejects without issues, I would then fire one live round and inspect the case and bolt face for signs of a problem. If all looks good, then fire a few more getting the gun warm. If it functions without a failure, I would be comfortable that the head spacing was within tolerances.
If you decide to use a live round for the first cycling test, remove the firing pin from the bolt before chambering.
Also check the hammer and sear engagement. Most are neutral and some are negative. If you aren't up for changing it to positive, at least know what your rifle has. Do not carry an SKS with a round in the chamber unless you are certain that it has positive engagement to avoid a AD. The safety only blocks the trigger and a bump to the rifle can cause the hammer to fall. A positive engagement makes this much less likely to occur, but does not absolutely prevent it.
Everyone should have an SKS. Tons of fun!